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Flammable and combustible liquids themselves do not burn. It is the mixture of their vapours and air that burns. Gasoline, with a flashpoint of -40°C (-40°F), is a flammable liquid. Even at temperatures as low as -40°C (-40°F), it gives off enough vapour to form a burnable mixture in air.




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mathnstuff
It is flammable because of the low flashpoint. Gasoline's flashpoint is -40 degrees Fahrenheit, which essentially means that the vapors released into the oxygenated air can be lit ablaze in low temperatures.